Aquatris(1H-benzimidazole-κN3)(dichloroacetato-κO)copper(II) dichloroacetate dihydrate
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چکیده
منابع مشابه
Tetraaquabis(1H-benzimidazole-5,6-dicarboxylato-κN 3)cobalt(II) dimethylformamide disolvate dihydrate
In the mononuclear title compound, [Co(C(9)H(4)N(2)O(4))(2)(H(2)O)(4)]·2C(3)H(7)NO·2H(2)O, the Co(II) atom, which lies on a center of inversion, is coordinated by four water mol-ecules and two N atoms from two two symmetry-related 1H-benzimidazole-5,6-dicarboxyl-ate ligands in a distorted octa-hedral geometry. The packing is governed by inter-molecular O-H⋯O and N-H⋯O hydrogen-bonding inter-act...
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In the title compound, [Cu(C(11)H(13)N(3))(2)](NO(3))(2)·2H(2)O, synthesized by hydro-thermal reaction of Cu(NO(3))(2) and racemic 2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole, the Cu(II) atom lies on an inversion centre. The distorted octa-hedral Cu(II) environment contains two planar trans-related N,N-chelating 2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole ligands in the equatorial plane and two monod...
متن کاملAquatris(1H-benzimidazole-κN 3)(dichloroacetato-κO)copper(II) dichloroacetate dihydrate
The title compound, [Cu(C(2)HCl(2)O(2))(C(7)H(6)N(2))(3)(H(2)O)]C(2)HCl(2)O(2)·2H(2)O, was prepared by reaction of copper(II) 2,2-dichloro-acetic acid and benzimidazole in ethanol solution. The compound shows a regular trigonal-bipyramidal stereochemistry. The Cu(II) centre possesses a five-coordinated environment, coordinated by three N atoms from the three benzimidazole ligands and two O atom...
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In the title compound, [CoCl(C(10)H(7)N(3)S)(2)]Cl·2H(2)O, the Co(II) atom is five-coordinated by four N atoms from two chelating 2-(1,3-thia-zol-4-yl)-1H-benzimidazole ligands and one Cl atom in a distorted trigonal-bipyramidal geometry. In the crystal, N-H⋯O and O-H⋯Cl hydrogen bonds and π-π inter-actions between the thia-zole, imidazole and benzene rings [centroid-to-centroid distances 3.546...
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And the same "case series" observations can be spun off, not later or through "data dredging," but at the same time, to create new hypotheses subject to subsequent data collection. And as new hypotheses are generated, the research consortium is in a position to collect the relevant data with few of the usual delays in forming a research team. By contrast, should the authors' proposals for resea...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809038392